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Zimmermann has agreed to terms on a deal with the Tigers that's expected to net him around $110 million over five years, Jon Morosi of Fox Sports reports.
Zimmermann has declined the qualifying offer extended to him by the Nationals, Mark Zuckerman of CSN Washington reports.
Zimmermann was given a qualifying offer by the Nationals on Friday, James Wagner of the Washington Post reports.
Zimmermann went six innings in a loss to the Braves on Wednesday, allowing two runs on six hits and a walk while striking out batter.
Zimmermann was battered for six runs on six hits, walking two and striking out six while lasting just five innings in an 8-2 loss to the Phillies on Friday night.
Zimmermann won his 13th game of the season Saturday, allowing two runs on six hits and a walk over six innings while striking out seven as the Nationals downed the Marlins 5-2.
Zimmermann (12-8) took a no-decision Monday night, giving up six earned runs on seven hits and a walk while striking out eight in an 8-7 win over the Phillies.
Zimmermann (12-8) pitched well over 5.2 innings Tuesday, allowing just one earned run on three hits while walking one and striking out six in an 8-7 loss to the Mets.
Zimmermann had an easy win fall in his lap in Thursday's blowout victory against the Braves, allowing one run and just two hits in six innings.
Zimmermann picked up his 11th win of the season Saturday, holding the Marlins to one run on seven hits and a walk over seven innings while striking out four.
Zimmermann will start Saturday against the Marlins, according to the Nationals' official website.
Zimmermann wasn't his best Sunday, but picked up his tenth win of the season after allowing four earned runs on eight hits and a walk, striking out seven over 5.2 innings.
Zimmermann allowed six runs (four earned) on nine hits and a walk over six innings in a no decision Tuesday against the Rockies.